Product ID:TT-L-20-COLOR 36375 LT GRAY, 110-708
MSDS Date:03/24/1992
FSC:8010
NIIN:00N042583
MSDS Number: BRNCD

D J SIMPSON CO

111 SOUTH MAPLE AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 415-873-5990

Preparer: PAUL GANSER

Cage: HO834

SIMPSON D J CO INC

2265 SOUTH SAN FRANCISCO, CA 94080-6303 US

Telephone: 415-873-5990

Cage: 33244

PRESENT MAY CAUSE PERM BRAIN/NERV SYS DAM (SOMETIMES

RTECS: 9999999ZZ

PROD CNTNS <1% BY WT OF METHANOL (CAS #(65-76-1).

RTECS: 9999999ZZ

PROD AND IS CLASSIFIED AS A CANCER HAZ BY

RTECS: 9999999ZZ

33@68F

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: <5.0%

OSHA PEL 400 PPM;500 PPM STEL

ACGIH TLV: 400 PPM;500 PPM STEL

5.1@68F

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 9%

OSHA PEL 100 PPM;150 PPM STEL

ACGIH TLV: 100 PPM;150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE). VP

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 20%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

22@68F

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 18%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

4.4@68F

CAS: 71-36-3

RTECS: EO1400000

Fraction By Weight: <5%

OSHA PEL 100 PPM

ACGIH TLV: S, C 50 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHANOL

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: <10%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BENZENE (PETROLEUM IMPURITY)

CAS: 71-43-2

RTECS: CY1400000

OSHA PEL 1 PPM;5 PPM STEL

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

5.12 LB/GL (613 G/L)

RTECS: 9999999VO

TOLUENE CAUSED HIGH FREQUENCY HEARING DEFICITS.

RTECS: 9999999ZZ

OF OCCUP CHEM REPROD HAZ. SEEK CONSULTATION FROM

RTECS: 9999999ZZ

INFO AND SAFE HANDLING AND EXPOSURE INFORMATION .

RTECS: 9999999ZZ

VOMITUS INTO LUNGS CAN CAUSE PNEUM WHICH

RTECS: 9999999ZZ

MADE, REMOVE SATURATED CLTHG & FLUSH AFFECTED

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:EXCESS INHAL OF VAPS CAN
CAUSE NASAL & RESP IRRIT, DIZZ, WEAK, FATG, NAUS & HDCH. HIGH CONC
MAY RSLT IN NARCOS. (CNS DEPRESS). EYE: REDDEN & BURNING SENSATION,
WATERING & BLURRED VISION. SKIN: DRY, REDDEN, IRRIT. SKIN ABSORP:
SEV IRRIT, DEFAT OF SKIN, DERM. INGEST: HDCH, DIZZ, NAUS, (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: VOMIT, DIARR. ASPIR OF MATL INTO
LUNGS CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. CHRONIC EXPOS MAY
CAUSE DAM TO CNS, RESP SYS, LUNGS, EYES, SKIN, GI TRACT, LIVER,
SPLEEN & KIDNEYS. RATS EXPOS ED TO XYLENE DURING PREGNANCY SHOWED
EMBRYO/FETOTOX EFTS. ANIMAL STUDIES HAVE SHOWN THAT INHAL OF HIGH
(SUPP DATA)
Medical Cond Aggravated by Exposure:SINUS AND LARYNGEAL CANCERS,
PRE-EXISTING HEART, LUNG, LIVER, AND SKIN DISORDERS.

First Aid:INHAL: REMOVE FROM EXPOS, RESTORE BRTHG; ADMINISTER OXYEN
WHEN NEC. SEEK MED HELP IMMED. EYE: WASH THORO W/LG AMTS OF WATER
FOR @ LST 15 MIN W/LIDS OPEN. SEEK MED HELP IMMED. SKIN: WASH W/LG
AMTS OF W ATER. WATCH FOR SKIN DE-OILING. IF IRRIT & DRY PERSISTS,
SEEK MED HELP. INGEST: GIVE 1-2 GLASSES OF WATER TO DILUTE. DO NOT
INDUCE VOMIT. SEEK MED HELP IMMED. KEEP QUIET & WARM. ASPIR OF (ING
12)

Flash Point Method:TCC
Flash Point:45F,7.2C
Lower Limits:1%
Upper Limits:11.2%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER MAY BE USED TO COOL CONTAINERS TO PREVENT PRESSURE BUILDUP,
POSS AUTOIGNIT/EXPLO DUE TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. KEEP WORK AREA FREE FROM SOURCES OF IGNIT. VAPS MAY
TRAVEL ALONG GROUND/BE MOVED BY VENT TO (SUPP DATA)

Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF
IGNITION. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING
TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CLOSURE TIGHT & CONTR IN UPRIGHT
POSITION. STORE AWAY FROM HEAT/OTHER SOURCES OF IGNIT. USE & STORE
PROD W/ ADEQ VENT.
Other Precautions:CONTR MUST BE GROUNDED &/OR BONDED DURING LIQ
TRANSFER. VAPS GIVEN OFF MAY TRAVEL ALONG GROUND/BE MOVED BY VENT
TO SOURCES OF IGNIT. EVEN RESIDUE MAY IGNITE EXPLOSIVELY! AVOID
PRLNGD BRTHG OF VAPS, SK IN/EYE CONT. SHOULD CONT BE (ING 13)

Respiratory Protection:NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTER
RESPIRATOR.
Ventilation:REQUIRED, 200 CFM MINIMUM.
Protective Gloves:CHEMICALLY IMPERVIOUS PLASTIC/RUBBER.
Eye Protection:CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:EYE WASH AND SAFETY SHOWERS IN WORK AREA ARE
RECOMMENDED.
Work Hygienic Practices:WASH WITH SOAP AND WATER, REMOVE CONTAMINATED
CLOTHING BEFORE HANDLING FOOD OR SMOKING.
Supplemental Safety and Health
EXPLO HAZ: SOURCES OF IGNIT. RESIDUE IN EMPTIED CONTRS CAN
EXPLODE/IGNITE EXPLOS. ALL 5-GALL PAILS & LGR METAL CONTRS MUST BE
GROUNDED &/OR BONDED DURING LIQ TRANSFER. EFTS OF OVERFEXP: LEVELS
OF TOLU ENE PRDCD CARDIAC SENSIT. SENSIT MAY CAUSE FETAL CHANGES IN
HEART RHYTHMS. PRLNGD EXPOS OF RATS TO XYLENE & (ING 9)

HCC:F3
Boiling Pt:B.P. Text:>180F,>82C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:1.1(H2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:TURBID LIQUID WITH DISTINCT SOLVENT ODDOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, ALKALIES AND SELECTED AMINES.
Stability Condition to Avoid:AVOID PROLONGED BREATHING OF VAPORS, SKIN/
EYE CONTACT. STORE AWAY FROM HEAT AND SOURCES OF IGNITION.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS LIKE CARBON
DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, SMOKE, TOXIC VAPORS
ANDD FUMES.

Waste Disposal Methods:DISPOSE I/A/W LOCALL, STATE AND FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.